At high overpotential (−0.5 V), the Li becomes more and more uneven with the increase of conductivity, as shown in Fig. 5. There are needle dendrites (Ω = 0.01) that have caused internal short circuit of the battery. The local current density is concentrated in the corner with large roughness and the tip of dendrite, as shown in Figs. 5 b and 5 c.
Continuum simulations demonstrate that the concave-convex patterned surface generates regular electrical field and associated current density fluctuations that suppresses tip-growth that otherwise is favored at pre-existing protrusions in planar foils.
Ultrathin surface coating of nitrogen-doped graphene enables stable zinc anodes for aqueous zinc-ion batteries Cotton-derived cellulose film as a dendrite-inhibiting separator to stabilize the zinc metal anode of aqueous zinc ion batteries
Metallic zinc is regarded as one of the most promising aqueous battery anodes, being abundant in the earth's crust (about 75 ppm), possessing a high theoretical capacity (820 mA h g −1) and low electrochemical potential (-0.76 V vs. SHE) [ 15, 16].
A highly reversible zn anode with intrinsically safe organic electrolyte for long-cycle-life batteries Dendrite growth in the recharging process of zinc-air batteries J. Mater. Chem. A, 3 ( 2015), pp. 22648 - 22655
In summary, this study reports a state-of-the-art performance zinc-ion battery (ZIB) based on a Laser Lithography Patterned Zinc Foils (LLP@ZF) from commercial zinc. In symmetric cells, LLP@ZF displays low plating/striping polarization and stable deep charge/discharge cycling.
Molecular Dipoles as a Surface Flattening and Interface …
MP molecular dipoles help increase the Li binding energy via concave sites and facilitate horizontal and flattened Li growth along the (110) surface instead of Li binding via the convex or terrace sites related to vertical …
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Understanding Charge-Transfer and Mass-Transfer Effects on …
Low ion conductivity enables the Li atoms deposit on the concave-convex surface uniformly by regulating the diffusion of Li-ions. The experimental results illustrate that dendrite growth and dead Li could reduce the capacity of Li metal battery. Coordination of charge …
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Enhanced cycling performance of cylindrical lithium-ion battery …
surrounds the convex surface of negative electrode, and the concave surface of the positive electrode is in a capacity exces-sive state, which causes the occurrence of lithium deposition. …
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« Concave » et « convexe » : quelle différence
Concave et convexe sont des paronymes et des antonymes, ce qui peut facilement prêter à confusion.. Concave : vers l''intérieur. Du latin concavus, « creux et rond ». Une surface est concave lorsqu''elle est arrondie à l''intérieur.La surface doit former un creux. Ce mot est tiré du latin classique concavus, qui signifie « creux et rond ».
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Evaluating performance and cycle life improvements in the latest ...
Efficiency of Lithium-Ion Batteries and of Electrode Materials for Lithium-Ion Batteries," Journal of The Electrochemical Society, vol. 157, no. 2, pp. A196-A202, 2010, doi: 10.1149/1.3268129.
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Molecular Dipoles as a Surface Flattening and Interface Stabilizing ...
MP molecular dipoles help increase the Li binding energy via concave sites and facilitate horizontal and flattened Li growth along the (110) surface instead of Li binding via the convex or terrace sites related to vertical dendrite growth. We also confirmed that the chemical composition of the SEI layer formed in the presence of MP was close to a strong carbonate- …
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γ-Graphyne nanotubes as promising lithium-ion battery anodes
Furthermore, we investigated Li diffusing in-plane and out-plane in the γGyNTs, and it was disclosed that the curvature can promote the diffusion and migration of the Li atom on the concave surface, which can further enhance the overall performance.
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LithiumBatteryElectrodeInspection
Lithium battery Electrode inspection system is an inline inspection system specialized for lithium battery positive and negative pole pre-coating, coating and die cutting process. Equipped with self-developed high-dynamic camera, patented light source, BatteryHero-Sep software system, high speed marking system, it has the characteristics of ...
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Concave vs Convex
Concave and Convex Functions Concave Functions. Examples: Exponential functions, quadratic functions with a positive leading coefficient. Properties: Slope increases as you move along the function. Holds the property f(tx+(1−t)y) ≥ tf(x) + (1−t)f(y) for 0 ≤t ≤1.; Ways to Remember: The shape of a concave function resembles the entrance to a cave or a hill.
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Understanding Charge-Transfer and Mass-Transfer Effects on …
Low ion conductivity enables the Li atoms deposit on the concave-convex surface uniformly by regulating the diffusion of Li-ions. The experimental results illustrate that dendrite growth and dead Li could reduce the capacity of Li metal battery. Coordination of charge-transfer coefficient, applied current density and SEI properties ...
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、、 (SEI) 。 …
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Lithium Storage in Bowl-like Carbon: The Effect of Surface …
We herein adopt carbon nanobowls (CBs) as a model host to study the geometry-guided Li growth behaviors by in situ electron microscopy. The strong effect of surface curvature is clearly demonstrated: Li metal is always guided to deposit on the concave surface of an isolated CB instead of the convex surface.
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、、 (SEI) 。 。 SEI。 。 , …
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Nanosecond laser lithography enables concave-convex zinc metal battery …
Continuum simulations demonstrate that the concave-convex patterned surface generates regular electrical field and associated current density fluctuations that suppresses tip-growth that otherwise is favored at pre-existing protrusions in planar foils. These attributes in sum ensure uniform zinc electrodeposition/electrostripping ...
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"Concave" vs. "Convex": What''s The Difference?
Concave and convex are literal opposites—one involves shapes that curve inward and the other involves shapes that curve outward. The terms can be used generally, but they''re often used in technical, scientific, and …
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Progress and Prospect of Zn Anode Modification in Aqueous Zinc …
Aqueous zinc-ion batteries (AZIBs), the favorite of next-generation energy storage devices, are popular among researchers owing to their environmental friendliness, low cost, and safety. However, AZIBs still face problems of low cathode capacity, fast attenuation, slow ion migration rate, and irregular dendrite growth on anodes. In recent years, many …
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γ-Graphyne nanotubes as promising lithium-ion battery anodes
Furthermore, we investigated Li diffusing in-plane and out-plane in the γGyNTs, and it was disclosed that the curvature can promote the diffusion and migration of the …
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Bending impact on the performance of a flexible Li4Ti5O12-based …
Here, we reveal that convex bending has a positive effect on battery capacity showing an average increase of 5.5%, whereas concave bending decreases the capacity by 4% in contrast with recent studies. We show that the change in capacity upon bending may well be associated to the Li-ion diffusion kinetic change through the electrode when ...
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Negative electrode of a concave surface in CC-A, b convex …
In this study, we propose a mass production-able and low-cost method to fabricate the anodes of Li-ion battery. Carbonaceous anodes, integrated with thin amorphous silicon layers by plasma...
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Negative electrode of a concave surface in CC-A, b …
In this study, we propose a mass production-able and low-cost method to fabricate the anodes of Li-ion battery. Carbonaceous anodes, integrated with thin amorphous silicon layers by plasma...
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Knowledge Center
A slight bulge in the battery container (convex end walls) can appear when the internal pressure is above the surrounding atmospheric pressure but not enough to open the PRV. Alternatively, the end walls can flex inward (concave end walls) when the internal pressure is less than surrounding atmospheric pressure. Both of these conditions are normal and do not affect the battery''s …
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Performance analysis of a novel concave-convex surface liquid …
In response to the critical need for efficient heat dissipation in high discharge rate Li-ion batteries, this study introduced a novel Concave-Convex Surface Liquid Cooling …
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Enhanced cycling performance of cylindrical lithium-ion battery …
surrounds the convex surface of negative electrode, and the concave surface of the positive electrode is in a capacity exces-sive state, which causes the occurrence of lithium deposition. Lithium dendrites [19–22] are formed by lithium deposition, which could reduce battery safety and electrochemical perfor-mance. Consequently, many ...
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Molecular Dipoles as a Surface Flattening and Interface Stabilizing ...
MP molecular dipoles help increase the Li binding energy via concave sites and facilitate horizontal and flattened Li growth along the (110) surface instead of Li binding via the convex or terrace sites related to vertical dendrite growth. We also confirmed that the chemical composition of the SEI layer formed in the presence of MP ...
Get Price
Lithium Storage in Bowl-like Carbon: The Effect of Surface …
We herein adopt carbon nanobowls (CBs) as a model host to study the geometry-guided Li growth behaviors by in situ electron microscopy. The strong effect of surface curvature is …
Get Price
Quantification of reversible and irreversible lithium in practical ...
An accurate evaluation of lithium-metal battery performance is challenging due to the excessive lithium that is often used at the anode. Here the authors report a methodology to assess the ...
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Performance analysis of a novel concave-convex surface liquid …
In response to the critical need for efficient heat dissipation in high discharge rate Li-ion batteries, this study introduced a novel Concave-Convex Surface Liquid Cooling Plate (CCS LCP). The CCS LCP was specifically designed to address the rapid temperature elevation and non-uniform thermal distribution observed in prismatic Li-ion battery ...
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Nanosecond laser lithography enables concave-convex zinc metal …
Continuum simulations demonstrate that the concave-convex patterned surface generates regular electrical field and associated current density fluctuations that suppresses …
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Bending impact on the performance of a flexible …
Here, we reveal that convex bending has a positive effect on battery capacity showing an average increase of 5.5%, whereas concave bending decreases the capacity by 4% in contrast with recent studies. We show that the change in …
Get Price