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Amino composite solid-state battery

In summary, this work proposes a novel PEO-LLZAO composite solid-state electrolytes (CSSEs) modified with acrylamide (AM)-contained ((3-methacrylamidopropyl) …

What is CSSE lithium battery?

Hydrogen bonding and coupling/crosslinking effects co-tailor the interface. Batteries with MTS-CSSE present fast and uniform Li + diffusion/deposition. All-solid-state lithium battery (ALLSB) with organic/inorganic composite solid-state electrolyte (CSSE) is one of the candidates for future energy storage due to the high specific energy and safety.

Which electrolyte is best for all-solid-state lithium battery (asslb)?

Lone pair electrons on N can complex with Li + and promote the dissociation of Li salts and uniform Li + diffusion. Composite solid-state electrolyte (CSSE) with integrated strengths avoids the weaknesses of organic and inorganic electrolytes, and thus become a better choice for all-solid-state lithium battery (ASSLB).

What is all-solid-state lithium battery (asslb)?

All-solid-state lithium battery (ASSLB) can effectively solve the safety problems of liquid system including electrolyte leakage, combustion and explosion, owing to the removal of liquid electrolyte.

What are organic/inorganic composite solid-state electrolytes?

The organic/inorganic composite solid-state electrolytes (CSSEs) which combine the flexibility of organic materials with the high conductivity and mechanical strength of the inorganic ones, have become a hot research [, , ].

How long does a Li/Li symmetrical battery last?

When subjected to a current density of 0.2 mA cm −2, a Li/Li symmetrical battery assembled with this composite electrolyte demonstrated stable operation for 1000 hours without experiencing any short circuits, which is double the performance of similar electrolytes containing LATP particles.

Are polyethylene oxide solid electrolytes suitable for all-solid-state lithium batteries?

Polyethylene oxide (PEO) solid electrolytes are regarded as a promising candidate for all-solid-state lithium batteries owing to their high safety and interfacial compatibility. However, PEO electrolyte is plagued by relatively weak structural strength and unsatisfactory Li + conductivity.

Composite solid-state electrolytes with fast ion channels …

In summary, this work proposes a novel PEO-LLZAO composite solid-state electrolytes (CSSEs) modified with acrylamide (AM)-contained ((3-methacrylamidopropyl) …

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Amino-modified UiO-66-NH2 reinforced polyurethane based …

Solid-state polymer electrolytes (SPEs) are candidate schemes for meeting the safety and energy density needs of advanced lithium-based battery because of their improved mechanical and electrochemical stability compared to traditional liquid electrolytes.

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A novel composite solid electrolyte based on chemical bonding …

Composite solid electrolyte (CSE) was composed of LPSC powders and PEO on PET matrix. Silane is introduced to finely tune the organic/inorganic interfaces in the CSE …

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The effects of amino groups and open metal sites of MOFs on

At last, we successfully designed a novel solid composite electrolyte containing activated NH 2 -MIL-101 (Fe), PEO, LiTFSI and PVDF for the high-performance all-solid-state lithium-metal batteries. This work might provide new insight to understand the interactions between polymers and functional groups or OMSs of MOFs better.

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Engineering the interface of organic/inorganic composite solid-state ...

Composite solid-state electrolyte (CSSE) with integrated strengths avoids the weaknesses of organic and inorganic electrolytes, and thus become a better choice for all-solid-state lithium battery (ASSLB). However, the poor dispersion of inorganic fillers and the organic/inorganic nature difference leads to their interface incompatibility, which ...

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Composite solid-state electrolytes for all solid-state lithium ...

The solid-state battery comprising a GO composite electrolyte demonstrates increased capacity (165 mA h g −1 after 50 cycles) and Coulombic efficiency (99.4%). …

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A novel composite solid electrolyte based on chemical bonding …

Composite solid electrolyte (CSE) was composed of LPSC powders and PEO on PET matrix. Silane is introduced to finely tune the organic/inorganic interfaces in the CSE via in situ coupling reaction. CSE have excellent ionic conductivity and lithium-ion transference number.

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A review of composite solid-state electrolytes for lithium batteries ...

All-solid-state lithium ion batteries (ASSLBs) are considered next-generation devices for energy storage due to their advantages in safety and potentially high energy density. As the key component in ASSLBs, solid-state electrolytes (SSEs) with non-flammability and good adaptability to lithium metal anodes have attracted extensive attention in recent years. Among the current …

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Composite solid-state electrolytes with fast ion channels …

In summary, this work proposes a novel PEO-LLZAO composite solid-state electrolytes (CSSEs) modified with acrylamide (AM)-contained ((3-methacrylamidopropyl) triethoxysilane (MTS)) to tailor the interfaces in all-solid-state lithium batteries (ASSLBs).

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Engineering the interface of organic/inorganic composite solid-state ...

In-situ polymerized composite polymer electrolyte with cesium-ion additive enables dual-interfacial compatibility in all-solid-state lithium-metal batteries. Integrating high ionic conductive PDOL solid/gel composite electrolyte for enhancement of interface combination and lithium dentrite inhibition of solid-state lithium battery.

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Amino-modified UiO-66-NH2 reinforced polyurethane based …

Solid-state polymer electrolytes (SPEs) are candidate schemes for meeting the safety and energy density needs of advanced lithium-based battery because of their improved …

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A room temperature rechargeable Li2O-based lithium-air battery …

Lithium-air batteries have scope to compete with gasoline in terms of energy density. However, in most systems, the reaction pathways either involve one- or two-electron transfer, leading to lithium peroxide (Li 2 O 2) or lithium superoxide (LiO 2), respectively.Kondori et al. investigated a lithium-air battery that uses a ceramic-polyethylene oxide–based …

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Composite solid-state electrolytes for all solid-state lithium ...

The solid-state battery comprising a GO composite electrolyte demonstrates increased capacity (165 mA h g −1 after 50 cycles) and Coulombic efficiency (99.4%). Interestingly, the combined use of CNTs and GO as fillers proves to have a synergistic effect, enhancing mechanical properties. 165 Wu et al. 166 introduced both carboxylated one …

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The effects of amino groups and open metal sites of MOFs on

At last, we successfully designed a novel solid composite electrolyte containing activated NH 2 -MIL-101 (Fe), PEO, LiTFSI and PVDF for the high-performance all-solid-state lithium-metal …

Get Price

Engineering the interface of organic/inorganic composite solid-state ...

The solid-state lithium battery assembled with polymer/garnet solid electrolyte and composite cathode framework demonstrates a high initial discharge capacity of 150.6 mAh g⁻¹ and good...

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Advanced Composite Solid Electrolyte Architecture …

After infiltrating by LiTFSI/PEO (LP), the LP/CN@B-NBC composite solid electrolyte (CSE) exhibits high lithium transference number and ionic conductivity. Upon coupling with LiFePO 4 cathode, the full battery …

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Composite solid electrolytes for all-solid-state lithium batteries

All-solid-state lithium sulfur batteries assembled with macro-structured composite sulfur cathode, MIL-53(Al)-PEO composite solid electrolyte and lithium anode delivered an initial discharge capacity of 1520 mA h g −1 at 0.2C (the battery tested at 80 °C).

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Advanced Composite Solid Electrolyte Architecture Constructed …

After infiltrating by LiTFSI/PEO (LP), the LP/CN@B-NBC composite solid electrolyte (CSE) exhibits high lithium transference number and ionic conductivity. Upon coupling with LiFePO 4 cathode, the full battery exhibits a remarkably high specific capacity, superior rate capability, and decent cycling stability.

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Engineering the interface of organic/inorganic composite solid-state ...

Composite solid-state electrolyte (CSSE) with integrated strengths avoids the weaknesses of organic and inorganic electrolytes, and thus become a better choice for all-solid-state lithium battery (ASSLB). However, the poor dispersion of inorganic fillers and the organic/inorganic nature difference leads to their interface ...

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Engineering the interface of organic/inorganic composite solid …

In-situ polymerized composite polymer electrolyte with cesium-ion additive enables dual-interfacial compatibility in all-solid-state lithium-metal batteries. Integrating high …

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Design of advanced composite battery materials based on …

Brief pre-LIBs and post-LIBs history in the context of porous functional materials and their transition to composite solid-state battery materials are depicted. The post-LIBs efforts mainly focus on the effective utilization of pre-LIBs materials to rationally design porous frameworks/cages/layered materials for the realization of solid-state batteries, with enhanced …

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Engineering the interface of organic/inorganic composite solid-state ...

Composite solid-state electrolyte (CSSE) with integrated strengths avoids the weaknesses of organic and inorganic electrolytes, and thus become a better choice for all-solid-state lithium battery (ASSLB). However, the poor dispersion of inorganic fillers and the organic/inorganic nature difference l … Engineering the interface of organic/inorganic composite solid-state …

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Advanced Composite Solid Electrolyte Architecture Constructed …

Polyethylene oxide (PEO) solid electrolytes are regarded as a promising candidate for all‐solid‐state lithium batteries owing to their high safety and interfacial compatibility. However, PEO electrolyte is plagued by relatively weak structural strength and unsatisfactory Li+ conductivity. Herein, a mechanically strong and Li+ conductively favorable cellulosic scaffold …

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Amino-modified UiO-66-NH2 reinforced polyurethane based

<p>Solid-state polymer electrolytes (SPEs) are candidate schemes for meeting the safety and energy density needs of advanced lithium-based battery because of their improved mechanical and electrochemical stability compared to traditional liquid electrolytes. However, low ionic conductivity and side reactions occurring in traditional high-voltage lithium metal batteries …

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Amino-modified UiO-66-NH2 reinforced polyurethane based

Amino-modified Zr-carboxylate metal-organic frameworks (MOFs) (UiO-66-NH 2) were designed as multifunctional fillers in forming a rich hydrogen bond network with polyurethane based electrolyte, achieving the collaborative promotion of the mechanical strength and room temperature ionic conductivity.

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Amino-modified UiO-66-NH2 reinforced polyurethane based

Amino-modified Zr-carboxylate metal-organic frameworks (MOFs) (UiO-66-NH 2) were designed as multifunctional fillers in forming a rich hydrogen bond network with polyurethane based …

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Engineering the interface of organic/inorganic composite solid-state ...

Composite solid-state electrolyte (CSSE) with integrated strengths avoids the weaknesses of organic and inorganic electrolytes, and thus become a better choice for all-solid-state lithium battery (ASSLB). However, the poor dispersion of inorganic fillers and the organic/inorganic nature difference leads to their interface incompatibility, which greatly destroys the …

Get Price

Engineering the interface of organic/inorganic composite solid-state ...

Composite solid-state electrolyte (CSSE) with integrated strengths avoids the weaknesses of organic and inorganic electrolytes, and thus become a better choice for all-solid-state lithium battery (ASSLB). However, the poor dispersion of inorganic fillers and the organic/inorganic nature difference leads to their interface incompatibility, which greatly …

Get Price

Engineering the interface of organic/inorganic composite solid …

The solid-state lithium battery assembled with polymer/garnet solid electrolyte and composite cathode framework demonstrates a high initial discharge capacity of 150.6 …

Get Price

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