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New negative electrode materials for zinc ion batteries

Among aqueous secondary batteries, zinc-based batteries are the most promising energy storage system in recent years. As the negative electrode of zinc-based …

Do zinc-ion battery electrolytes affect the cathode interface?

Current state of research on zinc-ion battery electrolytes and their effect on the cathode interface Electrolyte is an essential component of a battery, serving as the medium for connecting the positive and negative electrodes and facilitating ion transfer.

What is the electrode/electrolyte interface of aqueous zinc-ion battery systems?

However, studies on the electrode/electrolyte interface of aqueous zinc-ion battery systems have primarily focused on the surface of the zinc anode. This has been achieved through the construction of SEIs or the design of interfacial membranes with a uniform electric field and induced deposition to stabilize the zinc anode.

Can zinc negative electrodes be used as ZIB anodes?

These properties make them ideal for use as ZIB anodes with high speed performance and ruggedness . In summary, it is evident that the design of the zinc negative electrode can be improved through structural modifications, coatings, and electrolytes to mitigate issues such as zinc dendrites, passivation, and self-precipitation of hydrogen.

How to improve battery performance by modifying the zinc electrode?

Research on improving battery performance by modifying the zinc electrode can be based on three major directions: Improving the structure of the zinc electrode by using functional materials or materials with porous or layered structures; adding additives to the electrolyte to optimize the structure or morphology of the electrode; and zinc alloying.

Should aqueous zinc-ion batteries be used for electrical storage?

Aqueous zinc-ion batteries (AZIBs) have emerged as a practically attractive option for electrical storage because of environmentally benign aqueous-based electrolytes, high theoretical capacity of Zn anode, and significant global reserves of Zn. However, application of AZIBs at the grid-scale is restricted by drawbacks in cathode material (s).

Why do zinc ion batteries have a low voltage?

Due to the narrow thermodynamic stability window of water, the voltage of zinc-ion batteries is limited, and their charging and discharging processes are always coupled with the occurrence of side reactions such as hydrogen and oxygen precipitation.

Recent research on aqueous zinc-ion batteries and progress in ...

Among aqueous secondary batteries, zinc-based batteries are the most promising energy storage system in recent years. As the negative electrode of zinc-based …

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Production of fast-charge Zn-based aqueous batteries via ...

Aqueous zinc batteries attract interest because of their potential for cost-effective and safe electricity storage. Here, the authors develop an in situ formed ion-oligomer …

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Novel organic additives with high dipole moments: Improving the …

1 · The reversibility and stability of aqueous zinc-ion batteries (AZIBs) are largely limited by free-water-induced side reactions (e.g., hydrogen evolution and zinc corrosion) and negative zinc dendrite growth. To address these issues, we introduced triethyl 2-phosphonopropionate (Tp), a novel high-dipole-moment electrolyte additive. Tp effectively replaces free water in the …

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Highly Reversible Dendrite-Free Zinc Anode Enabled by a …

The unavoidable dendrite growth and side reactions are two major issues that lead to unsatisfactory cycling stability of the Zn metal anode and premature battery failure, which constrains the wide practical application of aqueous Zn-ion batteries. Herein, a bilayered zinc fluoride–indium interface-modified zinc anode (ZnF2–In@Zn) is in situ-constructed to solve …

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Cathode materials for aqueous zinc-ion batteries: A mini review

In aqueous aluminum-ion batteries, a protective oxide film is formed on the negative electrode; as a result, the efficiency and electrode potential of the battery are reduced, and uneven corrosion of aluminum will occur, which limits the large-scale application of aluminum ion batteries [26]. Similarly, for aqueous ZIBs, although zinc has the same ionic radius as …

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Porous Electrode Materials for Zn-Ion Batteries: …

Porous materials as electrode materials have demonstrated numerous benefits for high-performance Zn-ion batteries in recent years. In brief, porous materials as positive electrodes provide distinctive features such as …

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HEC/PAM hydrogel electrolyte toward regulating the surface of …

The new idea is provided for further development of functional hydrogel electrolytes in zinc-ion batteries. The inhomogeneous plating/stripping of zinc and side …

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Advancements in layered cathode materials for next-generation …

This review provides an overview of recent advancements in layered cathode materials for aqueous zinc-ion batteries, emphasizing structural characteristics, charge …

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Negative electrode materials for high-energy density Li

In the search for high-energy density Li-ion batteries, there are two battery components that must be optimized: cathode and anode. Currently available cathode materials for Li-ion batteries, such as LiNi 1/3 Mn 1/3 Co 1/3 O 2 (NMC) or LiNi 0.8 Co 0.8 Al 0.05 O 2 (NCA) can provide practical specific capacity values (C sp) of 170–200 mAh g −1, which produces …

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Unveiling Organic Electrode Materials in Aqueous Zinc-Ion …

In response to this, a strategic change has emerged, where traditional metal-ion battery negative electrodes are being replaced with environmentally safer metals, and organic …

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p‐Type Redox‐Active Organic Electrode Materials for …

1 Introduction. Efficient energy storage systems are crucial for realizing sustainable daily life using portable electronic devices, electric vehicles (EVs), and smart grids. [] The rapid development of lithium-ion batteries (LIBs) relying on inorganic electrode materials such as LiCoO 2, [2, 3] LiFePO 4, [] and LiMn 2 O 4 [] has facilitated inexpensive mobile energy storage devices with high ...

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Compressed composite carbon felt as a negative electrode for a zinc …

During charging, metallic zinc is electrodeposited onto the surface of a negative electrode while oxidized Fe 3+ is dissolved in the electrolyte. As its role in providing Zn electrodeposition, a ...

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Recent developments in carbon‐based electrodes …

Superior negative electrode materials with evenly dispersed zincophilic sites can prevent Zn dendrites and reduce HER. These materials promote uniform Zn deposition and suppress HER using strategies such as …

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MnO2 electrodeposition at the positive electrode of zinc-ion …

Manganese dioxide was the first positive electrode material investigated as a host for Zn 2+ insertion in the rechargeable zinc-ion battery (ZIB) with a zinc metal negative electrode [1,2,3]. The electrolyte in ZIBs is typically an aqueous solution of zinc sulfate or trifluoromethanesulfonate (triflate). Due to high availability, environmental and fire safety, low …

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HEC/PAM hydrogel electrolyte toward regulating the surface of zinc ...

The new idea is provided for further development of functional hydrogel electrolytes in zinc-ion batteries. The inhomogeneous plating/stripping of zinc and side reactions originating from the dissolution of the cathode material in water lead to the poor stability

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Highly Reversible Dendrite-Free Zinc Anode Enabled by a …

The unavoidable dendrite growth and side reactions are two major issues that lead to unsatisfactory cycling stability of the Zn metal anode and premature battery failure, …

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Developing Cathode Materials for Aqueous Zinc Ion …

Aqueous zinc-ion batteries (AZIBs) have emerged as a practically attractive option for electrical storage because of environmentally benign aqueous-based electrolytes, high theoretical capacity of Zn anode, and …

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Unveiling Organic Electrode Materials in Aqueous Zinc-Ion Batteries ...

In response to this, a strategic change has emerged, where traditional metal-ion battery negative electrodes are being replaced with environmentally safer metals, and organic electrolytes are being substituted with aqueous electrolytes. Aqueous rechargeable metal-ion batteries are a perfect fit for this innovative strategy.

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Recent research on aqueous zinc-ion batteries and progress in ...

Among aqueous secondary batteries, zinc-based batteries are the most promising energy storage system in recent years. As the negative electrode of zinc-based batteries, metallic zinc has low potential (-0.76 V vs. NHE), abundant reserves, and is …

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Production of fast-charge Zn-based aqueous batteries via

Aqueous zinc batteries attract interest because of their potential for cost-effective and safe electricity storage. Here, the authors develop an in situ formed ion-oligomer nanometric interphase ...

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Structural Modification of Negative Electrode for Zinc–Nickel …

In this paper, polarization of the positive and negative electrodes and the overall polarization of the battery are analyzed for the first time based on the three-dimensional transient model of ZNB.

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Preparation and research of anode materials for high …

The zinc negative electrode was modified by electron beam evaporation of the aluminum protective layer. The problems of low capacity and low energy density of zinc-ion batteries, zinc corrosion, and zinc dendrite formation during charge and discharge are solved, and the reversibility of the battery is improved.

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Structural Modification of Negative Electrode for Zinc–Nickel …

In this paper, polarization of the positive and negative electrodes and the overall polarization of the battery are analyzed for the first time based on the three-dimensional …

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Vanadate‐Based Fibrous Electrode Materials for High …

Vanadate-Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries. Qimeng Wang, Qimeng Wang. Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University, Nanjing, 211816 P. R. China . Search for more papers by this author. …

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Recent developments in carbon‐based electrodes surface …

Superior negative electrode materials with evenly dispersed zincophilic sites can prevent Zn dendrites and reduce HER. These materials promote uniform Zn deposition and suppress HER using strategies such as defect engineering and metal modification (see blue dashed box in Figure 1).

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Anode optimization strategies for zinc–air batteries

Since the reaction of zinc metal with alkaline solutions inevitably leads to the formation of ZnO and results in passivation, researchers have begun to look for alternative materials to zinc metal for the negative electrode of zinc–air batteries [92]. Currently, the main types of materials include calcium zincate, ZnO, and zinc alloys. For ...

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Developing Cathode Materials for Aqueous Zinc Ion Batteries: …

Aqueous zinc-ion batteries (AZIBs) have emerged as a practically attractive option for electrical storage because of environmentally benign aqueous-based electrolytes, high theoretical capacity of Zn anode, and significant global reserves of Zn. However, application of AZIBs at the grid-scale is restricted by drawbacks in cathode material (s).

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Recent Advances in Metal–Organic Framework Electrode Materials …

This study presents a collective review of the latest developments in the application of metal–organic frameworks (MOFs) in various metal-ion batteries (MIBs), including lithium-ion batteries (LIBs) and multivalent-ion batteries, from 2015 to 2023. First, the types of MOFs, standard fabrication methods, and electrochemical properties required for building …

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Advancements in layered cathode materials for next-generation …

This review provides an overview of recent advancements in layered cathode materials for aqueous zinc-ion batteries, emphasizing structural characteristics, charge storage mechanisms, and performance enhancement strategies. It briefly discusses benefits and obstacles and presents a systematic overview of various techniques from macro to micro ...

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